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Does E1 happen? Let's find out with a tertiary bromide, water and heat. The setup: water over the arrow, heat under it. Water is a weak base and a weak nucleophile, too weak to force the Br out. It waits for the substrate to make the first move. The substrate: Br sits on a tertiary carbon, a carbon bonded to three other carbons. Step 1. Br leaves with the bond's two electrons and becomes bromide, Br⁻. That carbon is down to three bonds, so it carries a plus: a carbocation. Three carbons hold tha
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